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dc.contributor.authorChen Guo-liang
dc.contributor.author陈国良
dc.contributor.authorLin Heng
dc.contributor.author林珩
dc.contributor.authorWen Li
dc.contributor.author文莉
dc.contributor.authorZheng Zi-shan
dc.contributor.author郑子山
dc.contributor.authorZhou Jian-zhang
dc.contributor.author周建章
dc.contributor.authorChen Sheng-pei
dc.contributor.author陈声培
dc.contributor.authorLin Zhong-hua
dc.contributor.author林仲华
dc.date.accessioned2011-07-01T04:25:59Z
dc.date.available2011-07-01T04:25:59Z
dc.date.issued2006
dc.identifier.citationSPECTROSCOPY AND SPECTRAL ANALYSIS,2006,26(10):1829-1832zh_CN
dc.identifier.issn1000-0593
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/9924
dc.description.abstractThe adsorption and oxidation of 1-butanol in alkaline media on a platinum electrode were investigated mainly by EQCM and in situ FTIR spectroscopy. The experimental results demonstrate that the electrooxidation of 1-butanol is closely relative to solution acidity. Since no chemically adsorbed species, such as CO, were evidenced by in situ FTIR spectroscopy, the adsorption of 1-butanol or its dissociative products on Pt surface is suggested by EQCM and CV data. Only one current peak of 1-butanol oxidation in PGPS was detected at -0.23 V/SCE, which illustrated the disappearance of the second current peak due to Pt electrode passivation in alkaline media. The final product of 1-butanol oxidation is only butyric acid anion under experimental condition. It may therefore be suggested that the main reaction occurring at the electrode is the oxidation of 1-butanol to butyric acid anion. The EQCM studies provide quantitative results of surface mass variation and have shed light on elucidating 1-butanol oxidation.zh_CN
dc.language.isozhzh_CN
dc.publisherBEIJING UNIV PRESSzh_CN
dc.subjectin-situ FTIRSzh_CN
dc.subjectEQCMzh_CN
dc.subjectPt electrodezh_CN
dc.subject1-butanolzh_CN
dc.subjectalkaline mediazh_CN
dc.subjectelectrooxidationzh_CN
dc.titleEQCM and in situ FTIR studies on the adsorption and oxidation of 1-butanol at a platinum electrode in alkaline mediazh_CN
dc.typeArticlezh_CN


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