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dc.contributor.authorLi Rongchun
dc.contributor.author李荣春
dc.contributor.authorYi Xiaodong
dc.contributor.author伊晓东
dc.contributor.authorZhang Xiaobing
dc.contributor.author章小兵
dc.contributor.authorHuang Chuanjing
dc.contributor.author黄传敬
dc.contributor.authorWeng Weizheng
dc.contributor.author翁维正
dc.contributor.authorWan Huilin
dc.contributor.author万惠霖
dc.date.accessioned2011-06-22T06:49:21Z
dc.date.available2011-06-22T06:49:21Z
dc.date.issued2006
dc.identifier.citationCHINESE JOURNAL OF CATALYSIS,2006,27(12):1069-1072zh_CN
dc.identifier.issn0253-9837
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/9723
dc.description.abstractTo elucidate possible reaction pathways for propane selective oxidation to acrolein over the MoPO/SiO2 catalyst, oxidative conversions of propane and possible intermediates or their probe molecules as well as the reaction products of the selective oxidation of propane to acrolein on the catalyst were studied. The results suggested that isopropoxy species is one of the intermediates for the selective oxidation of propane to acrolein over the MoPO/SiO2 catalyst. The isopropoxy species can be converted either to acetone by dehydrogenation or to propene by beta-hydrogen elimination, and the latter can be further converted to acrolein through an allylic process.zh_CN
dc.language.isozhzh_CN
dc.publisherSCIENCE CHINA PRESSzh_CN
dc.subjectmolybdenum oxidezh_CN
dc.subjectsilicazh_CN
dc.subjectphosphoruszh_CN
dc.subjectpropanezh_CN
dc.subjectselective oxidationzh_CN
dc.subjectacroleinzh_CN
dc.subjectreaction mechanismzh_CN
dc.titleReaction mechanism of selective oxidation of propane to acrolein over MoPO/SiO2 catalystzh_CN
dc.typeArticlezh_CN


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