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dc.contributor.authorSato, Osamu
dc.contributor.authorCui, Aili
dc.contributor.authorMatsuda, Ryotaro
dc.contributor.authorTao, Jun
dc.contributor.author陶军
dc.contributor.authorHayami, Shinya
dc.date.accessioned2011-06-07T13:27:50Z
dc.date.available2011-06-07T13:27:50Z
dc.date.issued2007-04
dc.identifier.citationACCOUNTS OF CHEMICAL RESEARCH,2007,40(5):361-369zh_CN
dc.identifier.issn0001-4842
dc.identifier.urihttp://dx.doi.org/doi:10.1021/ar600014m
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/9403
dc.description.abstractA number of photofunctional molecular compounds have been developed recently. Typical examples of these are phototunable valence tautomeric compounds, which are now attracting great attention. When the charge-transfer bands of some Co valence tautomeric compounds are excited at low temperature, metastable redox isomers can be created after irradiation. The lifetimes of the metastable states can be more than several hours. These transformations can involve changes in the magnetic properties of the compounds, as well as their color. Hence, these compounds can be regarded as novel photomagnetic materials. The photoresponsive behaviors of these valence tautomeric compounds are similar to those of spin-crossover complexes (light-induced excited spin-state trapping effects).zh_CN
dc.language.isoenzh_CN
dc.publisherAMER CHEMICAL SOCzh_CN
dc.titlePhoto-induced valence tautomerism in Co complexeszh_CN
dc.typeArticlezh_CN


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