Selective ligand conversion of ethylenediarnine tetraacetate to its triacetate on Peroxotitanate(IV)
Date
2007-07Author
Zhou, Zhao-Hui
周朝晖
Deng, Yuan-Fu
Liu, Qiong-Xin
Zhang, Hua-Lin
Mak, Thomas C. W.
Chow, Yuan L.
Collections
- 化学化工-已发表论文 [14469]
Abstract
Ethylenediaminetetraacetate is converted into its triacetate by peroxotitanate(IV), and strong chelation of the triacetate ligand to the metal center facilitates elimination of the pendant acetoxylate group. Various species of peroxotitanium(IV) complexes in the reaction sequence are fully characterized.