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Synthesis, crystal structure and optical properties of [Ag(UO2)(3)(OAc)(9)][Zn(H2O)(4)(CH3CH2OH)(2)]: A novel compound containing closed-shell 3d(10), 4d(10) and 5d(10) metal ions

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Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2] A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ions.pdf (196.6Kb)
Date
2007-08
Author
Luo, Geng-Geng
Lin, Li-Rong
林丽榕
Huang, Rong-Bin
黄荣彬
Zheng, Lan-Sun
郑兰孙
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  • 化学化工-已发表论文 [14469]
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Abstract
[Ag(UO2)(3) (OAc)(9)][Zn(H2O)(4)(CH3CH2OH)(2)] (1, OAc = CH3-COO-) crystallized from an ethanol solution and its structure was determined by IR spectroscopy, elemental analysis, H-1 NMR, C-13 NMR and X-ray crystallography; it is composed of [Zn(H2O)(4)(CH3CH2OH)(2)](2+) cations and [Ag(UO2)(3-)(OAc)(9)](2-) anions in which triuranyl [(UO2)(OAc)(3)](3) clusters are linked by the Ag ion.
Citation
DALTON TRANSACTIONS,2007,35:3868-3870
URI
http://dx.doi.org/doi: 10.1039/B708799C
https://dspace.xmu.edu.cn/handle/2288/9299

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