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Interesting anion-inclusion behavior of Cucurbit[5]uril and its lanthanide-capped molecular capsule

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Interesting anion-inclusion behavior of Cucurbit[5]uril and its lanthanide-capped molecular capsule.htm (392bytes)
Date
2007-10
Author
Liu, Jing-Xin
刘静欣
Long, La-Sheng
龙腊生
Huang, Rong-Bin
黄荣彬
Zheng, Lan-Sun
郑兰孙
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  • 化学化工-已发表论文 [14469]
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Abstract
The selective encapsulation behavior of cucurbit [5]uril and its lanthanide-capped molecular capsule toward nitrate and chloride ions has been investigated. Using fluorescence spectroscopy, the metal-free host has been demonstrated to selectively include nitrate ion. In contrast, the lanthanicle-capped molecular capsule showed preference toward the inclusion of chloride ion. Solid-state structures of the nitrate and chloride inclusion complexes with the La(III)-capped molecular capsule have been crystallographically determined.
Citation
INORGANIC CHEMISTRY,2007,46(24):10168-10173
URI
http://dx.doi.org/doi:10.1021/ic701236v
https://dspace.xmu.edu.cn/handle/2288/9228

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