A study on the N-, S- and Cl-modified nano-TiO2 coatings for corrosion protection of stainless steel
Date
2007-04Author
Yun, Hong
Li, Jing
Chen, Hong-Bo
Lin, Chang-Jian
林昌健
Collections
- 化学化工-已发表论文 [14469]
Abstract
Nano-titania coatings doped with anions of nitrogen, sulfur and chlorine have been supplied on the surface of 316L stainless steel by a sol-gel process and dip-coating technique. The measurements of XRD, SEM, ATR-IR, Raman and XPS were carried out to characterize the chemical composition and structure for the prepared samples. The corrosion performances of the coating in 0.5 M NaCl were evaluated by electrochemical impedance spectroscopy (EIS) and polarization measurements. According to the measurements of EIS and electrochemical polarization, the N-modified TiO2 nano-coatings show a highest corrosion resistance among the prepared coatings. It is revealed, from the SEM, XRD and Raman characterizations, that the surface of N-modified TiO2 nano-coatings are more compact and uniform, relatively well-crystallized and able to act as an optimal barrier layer to metallic substrates. The XPS analysis confirms the presence of low concentration of N element in two forms, atomic beta-N (interstitial state) and chemisorbed gamma-N-2 on the surface of TiO2 nano-coatings. It is suggested that the addition of nitrogen is beneficial to improve the compact structure and enhance the hydrophobic property. (c) 2007 Published by Elsevier Ltd.
Citation
ELECTROCHIMICA ACTA,2007,52(24):6679-6685URI
http://dx.doi.org/doi:10.1016/j.electacta.2007.04.078https://dspace.xmu.edu.cn/handle/2288/8979