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dc.contributor.authorLi, Xiangzh_CN
dc.contributor.authorSun, Zhichaozh_CN
dc.contributor.authorWang, Anjiezh_CN
dc.contributor.authorWang, Yaozh_CN
dc.contributor.authorDuan, Xinpingzh_CN
dc.contributor.authorChen, Yongyingzh_CN
dc.contributor.author段新平zh_CN
dc.date.accessioned2015-07-22T03:21:26Z
dc.date.available2015-07-22T03:21:26Z
dc.date.issued2014-01-05zh_CN
dc.identifier.citationCATALYSIS COMMUNICATIONS, 2014,43:21-24zh_CN
dc.identifier.otherWOS:000328527000005zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/89419
dc.descriptionNatural Science Foundation of China [20773020, 20973030, 21073022, 21173033, U1162203]; "863" project [2008AA030803]; NCET; Fundamental Research Funds for the Central Universities [DUT13LK18]; Ph.D. Programs Foundation (MOE) [20100041110016]; "111" projectzh_CN
dc.description.abstractNi2P/MCM-41 with a stoichiometric Ni/P ratio prepared using a H-2 plasma reduction method was passivated either by 10.0 vol.% H2S/H-2 (Ni2P-S) or 1.0 vol.% O-2/He (Ni2P-O). The XAS characterization demonstrated that the Ni-P bond of Ni2P was more sensitive to O-2 than the Ni-Ni bond while H2S mainly reacted with Ni-Ni site. Moreover, Ni species in Ni2P-S was more electron-deficient. The different hydrodesulfurization performances of Ni2P-S and Ni2P-O were discussed by considering their different structure and electronic properties as well as the formation of a covalent nickel phosphosulfide phase. (C) 2013 Elsevier B.V. All rights reserved.zh_CN
dc.language.isoen_USzh_CN
dc.publisherELSEVIER SCIENCE BVzh_CN
dc.source.urihttp://dx.doi.org/10.1016/j.catcom.2013.08.026zh_CN
dc.subjectNICKEL PHOSPHIDE CATALYSTSzh_CN
dc.subjectMETAL PHOSPHIDESzh_CN
dc.subjectHYDROGEN PLASMAzh_CN
dc.subjectHYDRODESULFURIZATIONzh_CN
dc.subjectSUPPORTzh_CN
dc.subjectNI2Pzh_CN
dc.subjectDIBENZOTHIOPHENEzh_CN
dc.subjectNANOPARTICLESzh_CN
dc.subjectPRECURSORSzh_CN
dc.subjectREDUCTIONzh_CN
dc.titleXAS study of Ni2P/MCM-41 passivated by O-2/He and H2S/H-2zh_CN
dc.typeArticlezh_CN


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