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dc.contributor.authorChen, Huzh_CN
dc.contributor.authorXu, Xunfuzh_CN
dc.contributor.authorLiu, Liuzh_CN
dc.contributor.authorTang, Guozh_CN
dc.contributor.authorZhao, Yufenzh_CN
dc.contributor.author唐果zh_CN
dc.contributor.author赵玉芬zh_CN
dc.date.accessioned2015-07-22T03:20:17Z
dc.date.available2015-07-22T03:20:17Z
dc.date.issued2013zh_CN
dc.identifier.citationRSC ADVANCES, 2013,3(37):16247-16250zh_CN
dc.identifier.otherWOS:000323842900004zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/88735
dc.descriptionChinese National Natural Science Foundation [21173178, 21232005]; Program for Changjiang Scholars and Innovative Research Team in University, Collaborative Innovation Center of Chemistry for Energy Materials, and Anhui [KJ2012B145, 2012rcjj03]zh_CN
dc.description.abstractA mild method is described for the conversion of carboxylic acids into esters, amides, as well as peptides without racemization through carboxyl activation by the reagent combination of POCl3 and DMAP. Long chain alcohols could be converted to the corresponding ester in good yields. P-31 NMR spectrum was used to detect phosphorus-containing intermediates in ongoing reactions directly, and a possible mechanism has been proposed based on these results.zh_CN
dc.language.isoen_USzh_CN
dc.publisherROYAL SOC CHEMISTRYzh_CN
dc.source.urihttp://dx.doi.org/10.1039/c3ra42887gzh_CN
dc.subjectCARBOXYLIC-ACIDSzh_CN
dc.subjectBOND FORMATIONzh_CN
dc.subjectESTERIFICATIONzh_CN
dc.subjectAMIDATIONzh_CN
dc.subjectALCOHOLSzh_CN
dc.subjectACTIVATIONzh_CN
dc.subjectPHOSPHATEzh_CN
dc.titlePhosphorus oxychloride as an efficient coupling reagent for the synthesis of esters, amides and peptides under mild conditionszh_CN
dc.typeArticlezh_CN


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