Show simple item record

dc.contributor.authorHuang, Yaozh_CN
dc.contributor.authorZhou, Yin-Ningzh_CN
dc.contributor.authorZhang, Qingzh_CN
dc.contributor.authorLuo, Zheng-Hongzh_CN
dc.contributor.author罗正鸿zh_CN
dc.date.accessioned2015-07-22T03:20:15Z
dc.date.available2015-07-22T03:20:15Z
dc.date.issued2013-Dec 5zh_CN
dc.identifier.citationJOURNAL OF APPLIED POLYMER SCIENCE, 2013,130(5):3473-3481zh_CN
dc.identifier.otherWOS:000324097400052zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/88718
dc.descriptionNational Ministry of Science and Technology of China [2012CB21500402]; National Natural Science Foundation of China [21276213, 21076171]zh_CN
dc.description.abstractTo investigate the process for the preparation of well-defined poly-dimethylsiloxane-b-2,2,3,3,4,4,4-heptafluorobutylmetharylate block copolymers via a macroinitiator initiated atom transfer radical polymerization (ATRP), a model for the batch and semi-batch ATRP process was presented based on the method of moments. The ATRP mechanism, the diffusion limitation, and the reactor choice were considered in the model. Besides, the polymer molecular weight, monomer conversion, and polymer polydispersity index as a function of polymerization time were described by this model. The model was validated by comparing simulated results with experimental data and was also used to investigate the effects of diffusion limitation and reactor choice (i.e., batch and semi-batch reactors). (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3473-3481, 2013zh_CN
dc.language.isoen_USzh_CN
dc.publisherWILEY-BLACKWELLzh_CN
dc.source.urihttp://dx.doi.org/10.1002/app.39602zh_CN
dc.subjectCHAIN COMPOSITION DISTRIBUTIONzh_CN
dc.subjectDIFFUSION-CONTROLLED REACTIONSzh_CN
dc.subjectLOW SURFACE-ENERGYzh_CN
dc.subjectBUTYL METHACRYLATEzh_CN
dc.subjectCOEFFICIENTSzh_CN
dc.subjectTEMPERATUREzh_CN
dc.subjectPREDICTIONzh_CN
dc.subjectACRYLATEzh_CN
dc.subjectBEHAVIORzh_CN
dc.subjectSYSTEMSzh_CN
dc.titleModeling of the atom transfer radical polymerization for preparing novel fluorosilicone diblock copolymers in a semi-batch reactorzh_CN
dc.typeArticlezh_CN


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record