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dc.contributor.author林志彬zh_CN
dc.contributor.author董燕青zh_CN
dc.contributor.author郑明森zh_CN
dc.contributor.author董全峰zh_CN
dc.contributor.authorLIN Zhi-binzh_CN
dc.contributor.authorDONG Yan-qingzh_CN
dc.contributor.authorZHENG Ming-senzh_CN
dc.contributor.authorDONG Quan-fengzh_CN
dc.date.accessioned2015-04-24T01:00:37Z
dc.date.available2015-04-24T01:00:37Z
dc.date.issued2015-04-28zh_CN
dc.identifier.citation电化学,2015,21(2):162-166.zh_CN
dc.identifier.issn1006-3471zh_CN
dc.identifier.urihttp://dx.doi.org/10.13208/j.electrochem.141209zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/84883
dc.description.abstract铂丝电极表面上电沉积一层金属钯,用阴离子交换隔膜材料封装,制得铂氢微型参比电极,工艺简单、稳定性高. 将该微型参比电极应用于全钒储能电池性能研究,可内置于电池多孔电极内部,监测电池正负极充放电性能. 结果显示,电池容量衰减主要归因于电解液中的活性物质V(IV)的逐渐减少及V(V)的积累导致正负极活性物质不平衡.zh_CN
dc.description.abstractA platinum-hydrogen reference micro-electrode was made with electroplating Pd on the surface of Pt wire and then coating anion membrane material. This reference electrode was built-in the porous electrode of the all vanadium redox flow batteries (VRFB), and monitored the charging /discharging and self-discharging of the VRFB. The results indicated that the capacity fading of VRFB occurred due to the graduate reduction of V(IV) active species in the electrolyte and the accumulation of V(V) in the positive electrode, leading to nonequilibrium of active species between the positive and negative electrodes.zh_CN
dc.language.isozhzh_CN
dc.publisher厦门大学《电化学》编辑部zh_CN
dc.relation.ispartofseries研究论文zh_CN
dc.relation.ispartofseriesArticleszh_CN
dc.source.urihttp://electrochem.xmu.edu.cn/CN/abstract/abstract10150.shtmlzh_CN
dc.subject参比电极zh_CN
dc.subject全钒液流电池zh_CN
dc.subjectPVP-PES隔膜zh_CN
dc.subjectreference electrodezh_CN
dc.subjectall vanadium redox flow batterieszh_CN
dc.subjectapplicationzh_CN
dc.title全钒液流电池铂氢微型参比电极体系的构筑与性能zh_CN
dc.title.alternativeA Platinum-Hydrogen Reference Micro-Electrode for All Vanadium Redox Flow Batteryzh_CN
dc.typeArticlezh_CN
dc.description.note作者联系地址:1. 厦门大学能源学院,福建 厦门 361005;2. 厦门大学化学化工学院,福建 厦门 361005zh_CN
dc.description.noteAuthor's Address: 1. College of Energy, Xiamen University, Xiamen 361005, Fujian, China; 2. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, Chinazh_CN
dc.description.note通讯作者E-mail:qfdong@xmu.edu.cnzh_CN


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