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dc.contributor.advisor詹庄平
dc.contributor.author郑飞剑
dc.date.accessioned2016-01-14T02:48:57Z
dc.date.available2016-01-14T02:48:57Z
dc.date.issued2014-02-26 10:59:07.0
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/76963
dc.description.abstract由于共轭芳环寡聚物具有优良的光电性能,因此研究合成这类化合物,就显得非常重要,并已经成为当前研究的热点之一。如果将芳香杂环引入芳环寡聚中,形成苯并取代杂环化合物,其电光性能和荧光量子产率均会有很大的提高。但目前对这五元环作为核心构件,进一步合成各种芳香环,双键或叁键交替相连的共轭寡聚物却鲜有报道。最近,我们实验室在“Lewisacid催化下,炔丙基醇类化合物的亲核取代反应及其后续的成环反应”这一领域,开展了系统性的研究。首先在催化量的FeCl3或者Cu(OTf)2作用下,生成呋喃前体,再经过PTSA催化,一锅法进行串联反应合成呋喃环,该法具有简便和经济的特点,特别是五元杂环结构具有多样性和可塑...
dc.description.abstractOligoaryls are an important class of heterocyclic compounds and there have been ever burgeoning study on the design and synthesis of benzene–furan oligomers for their potential optoelectronic applications. Incorporation of heteroaromatic compounds into these systems will occasionally increase fluorescence quantum yields and the optoelectronic properties of the oligomers can be tuned. We recently r...
dc.language.isozh_CN
dc.relation.urihttps://catalog.xmu.edu.cn/opac/openlink.php?strText=40084&doctype=ALL&strSearchType=callno
dc.source.urihttps://etd.xmu.edu.cn/detail.asp?serial=24157
dc.subject烯醇硅醚
dc.subject炔丙酯
dc.subject多取代呋喃
dc.subjectD-葡萄糖
dc.subject2-脱氧-D-葡萄糖。
dc.subjectPropargylic acetates
dc.subjectEnoxysilane
dc.subjectPolysubstituted furans
dc.subjectD-Glucose
dc.subject2-Deoxy-D-Glucose
dc.title苯取代呋喃寡聚物的合成和表征及从D-葡萄糖合成2-脱氧-D-葡萄糖
dc.title.alternativeSynthesis and Characterization of Benzene-furan Oligomers And Synthesis of 2-Deoxy-D-Glucose from D-Glucose
dc.typethesis
dc.date.replied2009-07-20
dc.description.note学位:理学硕士
dc.description.note院系专业:化学化工学院化学系_有机化学
dc.description.note学号:20520061151946


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