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dc.contributor.advisor温庭斌
dc.contributor.author王臻
dc.date.accessioned2016-01-14T02:48:43Z
dc.date.available2016-01-14T02:48:43Z
dc.date.issued2014-02-26 11:03:43.0
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/76893
dc.description.abstractC—X键(X=C,N,O,S,P,etc.)的形成是有机化学中最重要、最基础的研究内容之一。近年来,过渡金属参与的导向基团辅助的C—H键的活化及C—X键的形成反应取得重要进展。本论文以Rh的配合物为催化剂,探索并发展了几类导向基团辅助的C—H键的活化及C—C、C—N键的形成反应,并对部分反应机理进行了研究,全文共分为六章: 第一章为绪论,结合本论文的核心内容,阐述了C—H键活化的意义,总结了过渡金属参与的C—H键活化的几种途径,综述了近年来Ru,Pd,Fe,Cu,Rh催化的C—H键官能团化方面的研究进展,并简述了本论文的主要设想和目的。 第二章研究了Rh(III)/Cu(II)催化的由2-...
dc.description.abstractC-C and C-X(X = N, O, S, P, etc.)bond formation represents one of the most important and basic research subjects in organic chemistry. Significant progress have emerged on transition metal catalyzed C-H bond activation followed by C-X (X = C, N, O, S, P, etc.) bond formation in recent years. This dissertation mainly focuses on developing a series of novel Rh-catalyzed reactions involving C-H bond ...
dc.language.isozh_CN
dc.relation.urihttps://catalog.xmu.edu.cn/opac/openlink.php?strText=40076&doctype=ALL&strSearchType=callno
dc.source.urihttps://etd.xmu.edu.cn/detail.asp?serial=38220
dc.subject
dc.subjectC-H键活化
dc.subject2-吡啶甲酰基中氮茚
dc.subject吡啶[2,1-a]并异吲哚
dc.subject联芳基化合物
dc.subject共轭二烯
dc.subjectRhodium
dc.subjectC-H activation
dc.subject3-(Picolinoyl)indolizine
dc.subjectBiaryls
dc.subjectPyrido[2,1-a]isoindole
dc.subjectConjugated diene
dc.titleRh催化的C-H键的活化及C-C和C-N键的形成
dc.title.alternativeRh-Catalyzed C-H Bond Activation Followed by C-C and C-N Bond Formation
dc.typethesis
dc.date.replied2012-12-11
dc.description.note学位:理学博士
dc.description.note院系专业:化学化工学院化学系_有机化学
dc.description.note学号:20520090153353


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