Browsing 化学化工－已发表论文 by Title

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    • <0001>-Preferential Growth of CdSe Nanowires on Conducting Glass: Template-Free Electrodeposition and Application in Photovoltaics 

      Feng, Zengfang; Zhang, Qiaobao; Lin, Lingling; Quo, Honghui; Zhou, Jianzhang; Lin, Zhonghua; 林仲华 (AMER CHEMICAL SOC, 2010-04)
      By contrast with the rich, wurztite-related, one-dimensional nanostructure of ZnO and its wide variety of applications, there only exists a few methods for the controlled and designed synthesis of one-dimensional CdSe ...

    • (1)H, (13)C, (15)N backbone and side-chain resonance assignments of the human Raf-1 kinase inhibitor protein 

      Yi, Cuiying( Chinese Acad Sci, Shanghai Inst Mat Med); Peng, Yu( Chinese Acad Sci, Shanghai Inst Mat Med); Guo, Chenyun; Lin, Donghai; 林东海 (SPRINGER, 2011)
      Raf-1 kinase inhibitor protein (RKIP) plays a pivotal role in modulating multiple signaling networks. Here we report backbone and side chain resonance assignments of uniformly (15)N, (13)C labeled human RKIP.

    • (1)H-NMR-based metabonomic analysis of metabolic profiling in diabetic nephropathy rats induced by streptozotocin 

      Zhao, Liangcai（ Guangxi Med Univ, Affiliated Hosp 1）; Gao, Hongchang（ Wenzhou Med Coll, Sch Pharm）; Lian, Fulin（ Chinese Acad Sci, Shanghai Inst Mat Med）; Liu, Xia（ Chinese Acad Sci, Shanghai Inst Mat Med）; Zhao, Yongxiang（ Guangxi Med Univ, Affiliated Hosp 1）; Lin, Donghai; 林东海 (AMER PHYSIOLOGICAL SOC, 2011-01)
      Zhao L, Gao H, Lian F, Liu X, Zhao Y, Lin D. (1)H-NMR-based metabonomic analysis of metabolic profiling in diabetic nephropathy rats induced by streptozotocin. Am J Physiol Renal Physiol 300: F947-F956, 2011. First published ...

    • 1,1'-Ureylenedi-7,7-dimethylbicyclo 221 heptan-2-one 

      Gao, Y. X.; Liu, P.; Fang, Y. X.; Tang, G.; Zhao, Y. F.; 赵玉芬 (2007-10)
      The title compound, C19H28N2O3, was obtained by the acidic hydrolysis of (1S,4R)-1-isocyanato-7,7-dimethylbicyclo[2.2.1]heptan-2-one followed by addition of aqueous sodium hydroxide. N-H...O hydrogen bonds link the molecules ...

    • 1,1’-联萘-2,2’-二酚-单-[(-)-孟基]碳酸酯旋光异构体的反相高效液相色谱分离及光学纯度测定 

      阮源萍; 陈安齐; 刘文远; 郑锦丽; 黄培强 (厦门大学, 2000-11)
      采用反相高效液相色谱法分离了 1 ,1’-联萘 - 2 ,2’-二酚 -单 [(- ) -孟基 ]碳酸酯旋光异构体 .考察了这一对旋光化合物的反相高效液相色谱行为 .结果表明 ,C1 8及 C8柱和醇 /水流动相体系适合于这一对旋光异构体的分离 .进一步优化了色谱分离条件 ,并用于它们的光学纯度测定。 R)1,1’inaphthalene2,2’diolmono[()menthyl] carbonate and ...

    • 1,1’-联萘-2,2’-二酚及其孟基碳酸酯衍生物的手性高效液相色谱 

      阮源萍; 敖小平; 陈安齐; 黄培强; 靳立人 (厦门大学, 2002-03)
      用高效液相色谱法考察了 1,1’ 联萘 2 ,2’ 二酚及其单和双氯代孟基碳酸衍生物等三对手性化合物在 (S) 特 亮氨酸基 (S) 1 (α 萘基 )乙胺脲型手性色谱柱上的拆分行为 .讨论了三元流动相中 1,2 二氯乙烷和乙醇含量的变化以及不同极性调节剂对分离的影响 ,探讨了这些手性化合物在脲型手性固定相上的可能拆分机理 .该法已用于 ( ) 孟基氯代碳酸酯化学拆分外消旋 1,1’ 联萘 2 ,2’ 二酚过程相关产物的光学纯度测定. The ...

    • 1,2,3,4,4b,4c,6,7,8,9,9b,9c-Dodecachloro-4b,4c,9b,9c-tetrahydrocyclobuta[1,2-a;3,4-a']diindene-5,10-dione 

      Yin Peng; 彭银; Su-Yuan Xie; 谢素原; La-Sheng Long; 龙腊生; Rong-Bin Huang; 黄荣彬; Lan-Sun Zheng; 郑兰荪 (BLACKWELL MUNKSGAARD, 2004-08)
      The title compound, C18Cl12O2, was synthesized by a solvothermal reaction between sodium and carbon tetrachloride; the oxygen may come from air. The mol­ecule has crystallographic C2 symmetry and contains a four-membered ...

    • 1,2,3,5,6,7,8,9-octachlorocyclopenta[def]phenanthren-4-one 

      Yin Peng; 彭银; Su-Yuan Xie; 谢素原; Shun-Liu Deng; 邓顺柳; Rong-Bin Huang; 黄荣彬; Lan-Sun Zheng; 郑兰荪 (BLACKWELL MUNKSGAARD, 2004-05)
      The title compound, C15Cl8O, was separated from the products of a solvothermal reaction of metallic sodium and carbon tetrachloride in air in a pressured autoclave. The molecule is bisected by a crystallographic mirror ...

    • 1,2-二苯基乙二胺及与脱氢乙酸缩合生成的席夫碱化合物对映体的高效液相色谱法拆分 

      张磊; 谢宝竹; 阮源萍 (2006-09-30)

    • 1,2:3,4:5,6-Tri-O-isopropylidene-d-mannitol 

      Liu, P.; Wen, T. B.; Cheng, J. K.; 温庭斌 (1999)

    • 1,3,4,6,7,9-Hexabromo-2,3,4,5,6,7,8,9-octahydro-1H-trindene 

      Sheng-Jun Zhou; 周胜军; Su-Yuan Xie; 谢素原; Rong-Bin Huang; 黄荣彬; Lan-Sun Zheng; 郑兰荪 (BLACKWELL PUBLISHING, 2007-09)
      Each of the six Br atoms in the title compound, C15H12Br6, connects to an alpha-C atom; a pair of adjacent Br atoms connecting to the same five-membered ring extends to one side of the molecular framework and the other two ...

    • 1,3,5,7,9-五咔唑基心环烯的合成与表征 

      朱正钟; 李姝慧; 陈佐长; 徐云彦; 张前炎; 谢素原; 黄荣彬; 郑兰荪 (2019-02-13)
      自从作为富勒烯片段的心环烯分子被合成以来,大量具有C5对称性的碳-碳、碳-卤、碳-硼、碳-氧和碳-硫键修饰的心环烯衍生物陆续得到合成,然而具有C5对称性的碳-氮键修饰的心环烯衍生物至今还没有报道。本文通过五咔唑氮负离子对1,3,5,7,9-五氯心环烯的亲核取代反应实现了碳-氮键偶联并得到具有C5对称性的心环烯衍生物1,3,5,7,9-五咔唑基心环烯。该化合物的C5对称结构得到了核磁共振波谱、高分辨质谱的证实,其立体结构借助了密度泛函理论 ...

    • 1,3,5,7,9-五咔唑基心环烯的合成与表征 

      朱正钟; 李姝慧; 陈佐长; 徐云彦; 张前炎; 谢素原; 黄荣彬; 郑兰荪 (2019-02-13)
      自从作为富勒烯片段的心环烯分子被合成以来,大量具有C5对称性的碳—碳、碳—卤、碳—硼、碳—氧和碳—硫键修饰的心环烯衍生物陆续被合成,然而具有C5对称性的碳—氮键修饰的心环烯衍生物至今还没有报道.该研究通过五咔唑氮负离子对1,3,5,7,9-五氯心环烯的亲核取代反应实现了碳—氮键偶联,并得到具有C5对称性的心环烯衍生物1,3,5,7,9-五咔唑基心环烯.采用核磁共振波谱和高分辨质谱进行表征证实其具有C5对称结构,并采用密度泛函理论（DFT ...

    • 1,3-di-2-pyridylthiourea monohydrate 

      Zhong, HP; Long, LS; 龙腊生; Huang, RB; 黄荣彬; Zheng, LS; 郑兰荪; Ng, SW (BLACKWELL MUNKSGAARD, 2003)
      The title compound, C11H10N4S.H2O, displays an intramoleculear N-amido...N-pyridyl hydrogen bond [2.652 (2) Angstrom] that locks the thiourea unit and one pyridyl ring into coplanarity [dihedral angle 2.7 (1)degrees]. The ...

    • 1,3-Propanediol adsorption on a cation exchange resin: Adsorption isotherm, thermodynamics, and mechanistic studies 

      Wang, Shizh; Dai, Hongfei; Yan, Zhengping; Zhu, Chunjie; Huang, Lingf; Fang, Baish; 王世珍; 黄凌风; 方柏山 (Wiley-VCH Verlag, 2014 Septe)
      1,3-Propanediol (1,3-PD) is widely used in cosmetics, foods, antifreezes, and polyester. A low-cost cation exchange resin, 001×7 H-form resin, was selected for 1,3-PD adsorption obtained from microbial fermentation of crude ...

    • 1,4-diazoniabicyclo[222]octane terephthalate 

      Yang, E.; Song, Xu-Chun; Zhu, Jian-Wei; 朱建伟 (ACTA CRYSTALLOGR E, 2008-09)
      In the title compound, C(6)H(14)N(2+) center dot C(8)H(4)O(4)(2 -), the protonated 1,4-diazoniabicyclo[ 2.2.2] octane cations and the deprotonated terephthalate anions are alternately linked by N - H center dot center dot ...

    • 1,4-丁二醇在Pt及其修饰电极上吸附氧化过程研究 

      林珩; 陈声培; 林进妹; 林爱兰; 黄如莺; 陈国良 (2003-09-23)
      　运用电化学循环伏安和石英晶体微天平研究了1,4-丁二醇(1,4-BDL)在Pt电极及以Sb和S吸附原子修饰的Pt(Pt/Sbad和Pt/Sad)电极上的吸附和氧化过程.结果表明,1,4-丁二醇的氧化与电极表面氧物种有着极其密切的关系,表面质量变化提供了吸附原子电催化作用的新数据.Pt电极表面Sb吸附原子能在较低的电位下吸附氧,可显著提高1,4-丁二醇电催化氧化活性.与Pt电极相比,1,4-丁二醇在饱和吸附Sb原子的Pt电极上氧化的峰电位负移了0 ...

    • 1,4-丁炔二醇温和条件下Pd-Ni基加氢催化剂的研究 

      郭家威; 张蕾; 南军; 叶松寿; 郑进保; 陈秉辉 (2019-04-29)
      鉴于1,4-丁炔二醇加氢制1,4-丁二醇的生产工艺一般涉及高压高温,分别以α-Al2O3和碳纳米管(CNTs)为载体,研究了近室温(30℃)近常压(0.2MPa)下1,4-丁炔二醇的Pd(Ni)基催化剂的加氢性能及其结构特征.结果发现,Pd-Ni双金属催化剂可以实现1,4-丁炔二醇的完全转化.对于产物1,4-丁二醇的选择性,还原法制备的1%Pd-1%Ni/CNTs仅达60.6%,而分步浸渍法制备的1%Pd-1%Ni/α-Al2O3和1% ...

    • 1,4-丁炔二醇温和条件下PdNi基加氢催化剂的研究 

      郭家威; 张蕾; 南军; 叶松寿; 郑进保; 陈秉辉 (2019-04-29)
      鉴于丁炔二醇加氢制丁二醇的生产工艺一般涉及高压/高温,以α-Al2O3或碳纳米管（CNTs）为载体,研发了近室温近常压下1,4-丁炔二醇的Pd（Ni）基催化剂的加氢性能及其结构特征。结果发现,双金属PdNi基催化剂可以实现丁炔二醇的完全转化。对于产物丁二醇的选择性,还原法制备的PdNi/CNTs仅达60.6%,而浸渍法制备PdNi/α-Al2O3和PdNi/CNTs则可达89.1%和98.9%。X射线衍射（XRD）、氢气程序升温还原（H ...

    • 1,4-二氧六环介质中辣根过氧化物酶电极的性能研究 

      陈红; 吴辉煌 (1996)
      用交联法制备辣根过氧化物酶(HrP)电极,在1,4-二氧六环介质中研究其电化学行为.实验表明,固定化的HrP在有机相中仍保持活性并可与电极进行直接电子传递,因而能在没有其它电子传递体存在的条件下催化H_2O_2的电化学还原反应.当亚铁氰化物与酶共修饰至电极上之后,它起着电子传递体的作用,使HrP电极的性能大为改善.根据不同条件下得到的动力学参数,讨论了影响酶电极性能的因素.