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dc.contributor.author王欢zh_CN
dc.contributor.author朱美侠zh_CN
dc.contributor.author吴腊霞zh_CN
dc.contributor.author徐晓明zh_CN
dc.contributor.author赵学如zh_CN
dc.contributor.author陆嘉星zh_CN
dc.contributor.authorWANG Huanzh_CN
dc.contributor.authorZHU Mei-xiazh_CN
dc.contributor.authorWU La-xiazh_CN
dc.contributor.authorXU Xiao-mingzh_CN
dc.contributor.authorZHAO Xue-ruzh_CN
dc.contributor.authorLU Jia-xingzh_CN
dc.date.accessioned2013-11-18T07:48:00Z
dc.date.available2013-11-18T07:48:00Z
dc.date.issued2013-08-28zh_CN
dc.identifier.citation电化学,2013,19(4):328-331.zh_CN
dc.identifier.issn1006-3471zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/58597
dc.description.abstract在常温常压下,采用电化学方法,以丙三醇和CO2为原料合成了丙三醇碳酸酯,并详细考察了各种条件对该反应的影响规律. 择优条件下,目标碳酸酯的产率可达73%,远远高于普通的催化方法. 并借助循环伏安曲线研究了反应体系的电化学行为,分析了整个反应的可能历程.zh_CN
dc.description.abstractGlycerol carbonate was obtained from glycerol and carbon dioxide under room temperature and normal pressure by electrochemical method. The effects of synthesis conditions, such as cathode, charge, current density and temperature, on the reaction of glycerol and carbon dioxide have been investigated. The yields of 73% were produced by electrosynthesis of carbonate under the optimized condition, which is much higher than that by common catalysis method. The electrochemical behavior of the reaction system has been studied by cyclic voltammetry, through which the reaction process has been proposed.zh_CN
dc.description.sponsorship国家自然科学基金项目(No. 211730885,No. 21203066)资助zh_CN
dc.language.isozhzh_CN
dc.publisher厦门大学《电化学》编辑部zh_CN
dc.relation.ispartofseries环境电化学近期研究专辑(吉林大学 林海波教授主编)zh_CN
dc.relation.ispartofseriesSpecial Issue of Environmental Electrochemistry (Editor: Professor LIN Hai-bo, JilinUniversity)zh_CN
dc.source.urihttp://electrochem.xmu.edu.cn/CN/abstract/abstract9982.shtmlzh_CN
dc.subject丙三醇zh_CN
dc.subject二氧化碳zh_CN
dc.subject电合成zh_CN
dc.subject有机碳酸酯zh_CN
dc.subjectglycerolzh_CN
dc.subjectcarbon dioxidezh_CN
dc.subjectelectrosynthesiszh_CN
dc.subjectorganic carbonatezh_CN
dc.title丙三醇碳酸酯的电合成研究zh_CN
dc.title.alternativeElectrosynthesis of Glycerol Carbonate from CO2 and Glycerolzh_CN
dc.typeArticlezh_CN
dc.description.note作者联系地址:上海市绿色化学与化工过程绿色化重点实验室,华东师范大学化学系,上海 200062zh_CN
dc.description.noteAuthor's Address: Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, Chinazh_CN
dc.description.note通讯作者E-mail:jxlu@chem.ecnu.eud.cnzh_CN


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