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dc.contributor.author张兴芳zh_CN
dc.contributor.author梁镇海zh_CN
dc.contributor.author石文平zh_CN
dc.contributor.author樊彩梅zh_CN
dc.contributor.authorZHANG Xing-fangzh_CN
dc.contributor.authorLIANG Zhen-haizh_CN
dc.contributor.authorSHI Wen-pingzh_CN
dc.contributor.authorFAN Cai-meizh_CN
dc.date.accessioned2013-11-18T07:46:50Z
dc.date.available2013-11-18T07:46:50Z
dc.date.issued2009-08-28zh_CN
dc.identifier.citation电化学,2009,15(03):336-340.zh_CN
dc.identifier.issn1006-3471zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/58251
dc.description.abstract应用Monte Carlo方法,结合化学反应随机过程理论,模拟钛电极上苯酚电催化氧化反应机理,研究苯酚降解时间、初始浓度、电极的催化性能及反应中间产物对降解过程的影响.结果表明:苯酚浓度随时间变化逐渐降低并渐趋稳定,苯酚初始浓度较高时降解速率快,具有较高催化性能的电极对降解第1步反应的影响较大,可有效减少中间产物停留时间,但控制第1步反应则对降解过程尤其是第2步反应的产物有明显影响,而控制第2步反应对降解过程影响很小.zh_CN
dc.description.abstractAccording to Monte Carlo mechanism and random process theory,the mechanism of phenol degradation on titanium electrode was simulated. The effects of degradation time,initial concentration of phenol,electrode performance and intermediates on the process of degradation were determined. The results indicated that the phenol concentration is decreasing and becoming steady during the degradation process,if increase the initial concentration,the degradation rate is also increased at the beginning of reaction process,the electrodes with high performance strongly affect the first step of degradation by reducing the residence time of intermediates,the whole process and the productions of second step are primarily controlled by the first step of reaction,and the effect of second step on the whole process is minor.zh_CN
dc.language.isozhzh_CN
dc.publisher厦门大学《电化学》编辑部zh_CN
dc.relation.ispartofseries研究论文zh_CN
dc.relation.ispartofseriesArticleszh_CN
dc.source.urihttp://electrochem.xmu.edu.cn/CN/abstract/abstract8513.shtmlzh_CN
dc.subjectMonte Carlo模拟zh_CN
dc.subject降解机理zh_CN
dc.subject苯酚zh_CN
dc.subject钛电极zh_CN
dc.subjectMonte Carlo simulationzh_CN
dc.subjectdegradation mechanismzh_CN
dc.subjectphenolzh_CN
dc.subjecttitanium electrodezh_CN
dc.title钛电极苯酚降解反应动力学的Monte Carlo模拟zh_CN
dc.title.alternativeMonte Carlo Simulation of Kinetics of Phenol Degradation on Titanium Based Anodezh_CN
dc.typeArticlezh_CN
dc.description.note作者联系地址:太原理工大学化学化工学院;zh_CN
dc.description.noteAuthor's Address: College of Chemistry and Chemical Engineering,Taiyuan University of Technology,Taiyuan 030024,Chinazh_CN


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