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dc.contributor.author刘景东zh_CN
dc.contributor.authorLIU Jing-dongzh_CN
dc.date.accessioned2013-11-18T07:46:17Z
dc.date.available2013-11-18T07:46:17Z
dc.date.issued2007-11-28zh_CN
dc.identifier.citation电化学,2007,13(04):420-424.zh_CN
dc.identifier.issn1006-3471zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/58054
dc.description.abstract应用点缺陷模型和双层模型分析了金属│固体电解质│含水凝胶│石墨体系贮藏和放电时金属表面氧化膜的变化.在固体电解质含有微量水分的情况下,微量水分有助于金属表面形成松层,但由于水分子与紧密钝化膜的持续作用,金属表面松层厚度会不断增长,孔率降低,使得电池的电压和放电电流下降.松层的孔率强烈影响膜溶解行为,与紧密钝化膜的电学特性一样,松层也是一种半导体.zh_CN
dc.description.abstractThe characteristic of oxide layer formed on the surface of metal in Metal|Solid Electrolyte|Gel Membrane Containing Water|Graphite System was studied by using Point Defect Model and Barrier Layer/Porous Layer Model.Trace water in solid electrolyte helped to form porous layer at the surface of metal,The thickness of porous layer increased due to water molecule reacts with barrier layer continuously,which lowered the porosity and decreased the electromotive potential and current.Porosity influenced solubility behavior of oxide layer intensely.Like barrier layer,porous layer is also a semiconductor.zh_CN
dc.language.isozhzh_CN
dc.publisher厦门大学《电化学》编辑部zh_CN
dc.relation.ispartofseries研究论文zh_CN
dc.relation.ispartofseriesArticleszh_CN
dc.source.urihttp://electrochem.xmu.edu.cn/CN/abstract/abstract8692.shtmlzh_CN
dc.subject点缺陷模型zh_CN
dc.subject双层模型zh_CN
dc.subject钝化膜zh_CN
dc.subject镁电极zh_CN
dc.subject锂水电池zh_CN
dc.subjectpoint defect modelzh_CN
dc.subjectbarrier layer/porous layer modelzh_CN
dc.subjectpassive filmzh_CN
dc.subjectmagnesium electrodezh_CN
dc.subjectlithium/water batteryzh_CN
dc.title金属│固体电解质│含水凝胶│石墨体系的研究zh_CN
dc.title.alternativeStudy on Metal|Solid Electrolyte|Gel Membrane Containing Water|Graphite Systemzh_CN
dc.typeArticlezh_CN
dc.description.note作者联系地址:福州大学化学化工学院 福建福州350002zh_CN
dc.description.noteAuthor's Address: School of Chemistry & Chemical Engineering,Fuzhou University,Fuzhou 350002,Chinazh_CN


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