Electrochemical Reduction of Nitrobenzene on the WC Electrode in Acidic Solution
- 2004年第10卷 
以聚四氟乙烯为粘接剂制成碳化钨(WC)电极.采用循环伏安法、线性扫描法和恒电位阶跃法研究了硝基苯在酸性溶液中WC电极上的电化学行为.实验表明:WC电极对硝基苯的还原具有较好的活性,电极过程受扩散和电化学步骤混合控制;表观活化能为23.7kJ·mol 1,其中,电化学步骤的活化能10.91kJ·mol 1.The tungsten carbide (WC) electrode was constructed by using polyterafluoroethylene as binder. The electrochemical behavior of nitrobenzene on the WC electrode in acidic solution was investigated by cyclic voltammetry, linear scan method and chronoamperometry. Experimental results showed that WC electrode had good activity for the electrochemical reduction of nitrobenzene, and the electrode process was controlled by diffusion and electrochemical stepssimultaneously. The apparent active energy of the electrode process is 23.7kJ mol~(-1), while the active energy of the electrochemicalstep is 10.91kJ mol~(-1).