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dc.contributor.author杨防祖zh_CN
dc.contributor.author吴辉煌zh_CN
dc.contributor.author许书楷zh_CN
dc.contributor.author周绍民zh_CN
dc.contributor.authorYangFangzuzh_CN
dc.contributor.authorWuHuihuangzh_CN
dc.contributor.authorXuShukaizh_CN
dc.contributor.authorZhouShsominzh_CN
dc.date.accessioned2013-11-18T07:43:35Z
dc.date.available2013-11-18T07:43:35Z
dc.date.issued1996-08-28zh_CN
dc.identifier.citation电化学,1996,2(03):294-298.zh_CN
dc.identifier.issn1006-3471zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/57220
dc.description.abstract用伏安法分别研究N,N′-二甲基甲酰胺和1,4-二氧六环介质中还原态烟酰胺辅酶NADH在玻碳电极上的电化学氧化行为并测定某些动力学参数。NADH的电氧化表现为完全不可逆过程,实验证明其过程伴有快速化学步骤。与在1,4-二氧六环介质中的相比,NADH在N,N′-二甲基甲酰胺介质中的电氧化速度和扩散系数较小,但电流响应较为稳定。根据溶剂效应讨论了上述实验结果。zh_CN
dc.description.abstractThe behaviour of electrochemical oxidation of the reduced nicotinamide coenzyme NADH on glassy carbon was studied and some kinetic parameters were measured by means of voltammometry in the N-dimethylformamide(DMF)and 1,4-dioxane media respectively. The eletrochemical oxidation of NADH shows completely irriversable both in the two solvents,and the diagnostic experiments support that the process involves a fast chemical step.The oxidation rate and the diffusion coefficient of N ADH in DMP are smaller than those in 1,4-dioxane,but the response current is more stable in DMF. The experimental results are discussed by solvent effects.zh_CN
dc.language.isozhzh_CN
dc.publisher厦门大学《电化学》编辑部zh_CN
dc.relation.ispartofseries研究论文zh_CN
dc.relation.ispartofseriesArticleszh_CN
dc.source.urihttp://electrochem.xmu.edu.cn/CN/abstract/abstract9633.shtmlzh_CN
dc.subjectNADHzh_CN
dc.subject电化学氧化zh_CN
dc.subject有机相酶学zh_CN
dc.subject生物电化学zh_CN
dc.subjectNADHzh_CN
dc.subjectElectrochemical oxidationzh_CN
dc.subjectorganic phase enzymologyzh_CN
dc.subjectbioeletrochemistryzh_CN
dc.title有机介质中辅酶NADH的电化学氧化zh_CN
dc.title.alternativeA Study on Electrochemical Oxidation of Reduced Nicotinamide Coenzyme NADH in Organic Mediazh_CN
dc.typeArticlezh_CN
dc.description.note作者联系地址:厦门大学固体表面物理化学国家重点实验室zh_CN
dc.description.noteAuthor's Address: Dept.of Chem.,State Key Laboratory for Physical Chemistry of Solid Surface,Xiamen University,Xiamen 361005zh_CN


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