Study of Electrochemistry of Octa Butyl 2, 3 Naphthalocyanine Manganese(Ⅲ) in Nonaqeous Solvents
- 1996年第2卷 
非水溶剂中八丁氧基２，３萘酞菁氯锰（Ⅲ）的电化学研究①杨素苓刘尔生陈耐生黄金陵（福州大学化学系，福州３５０００２）王晓玉卜平段武彪吴谊群左霞（黑龙江大学化学系，哈尔滨１５００８０）金属萘酞菁配合物由于含有比相应的酞菁配合物更大的π共轭体系，因而具...The electrochemical behavior of 5,9,14,18,23,27,32,36 Octa Butyl 2,3 Naphalocyanine Manganese (Ⅲ) [(BuO) 8NPcMn(Ⅲ)Cl] in four nonaqueous solvents was studied by means of cyclic voltammetry, and the corresponding half wave potentials (E 1/2 ) of redox reactions were obtained. Four (or five) pairs of redox peaks were assigned. The solvent effect on the electrochemical characteristics of this coordination compound was also discussed preliminarily, and the electrochemical behavior of the complex was compared with that of nonsubstitued naphthalocyanine.