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dc.contributor.author蔡文斌zh_CN
dc.contributor.author柳厚田zh_CN
dc.contributor.author周伟舫zh_CN
dc.contributor.authorCai Wenbinzh_CN
dc.contributor.authorLiu Houtianzh_CN
dc.contributor.authorZhou Weifangzh_CN
dc.date.accessioned2013-11-18T07:43:22Z
dc.date.available2013-11-18T07:43:22Z
dc.date.issued1995-08-28zh_CN
dc.identifier.citation电化学,1995,1(03):259-263.zh_CN
dc.identifier.issn1006-3471zh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/57148
dc.description.abstract基于铅酸电池的实际应用以及对铅本身电化学行为的兴趣,人们对铅及其合金在硫酸溶液中形成的阳极膜,已做了大量的研究 ̄[1~4]。其三大进展为:Fleischmann与Thirsk ̄[5]提出成核与生长机理来解释β-PbO_2的形成;Pavlov ̄[6]采用光电化学方法研究PbO电位区的固相反应;Ruetschi ̄[7]提出阳极膜最外层PbSO_4为半透膜,保证膜内部的碱性环境。然而总的来说,各个研究者对铅阳极膜缺乏统一的认识。其主要原因是铅阳极膜相组成复杂,至今尚未完全确定。有鉴于此,我们将陆续介绍本小组对于硫酸溶液中铅阳极膜研究的几个问题所持的观点。zh_CN
dc.description.abstractThe identification of the phase composition of the anodic film on Pb formed inH_2SO_4 solution in PbO potential region has long been argued,together with the explanation of thecathodic peak at about -0.9V(Hg/Hg_2SO_4)in the linear sweep voltammogram for a Pb-H_2SO_4system. In this article, a review of our recent investigations was presented on the above problems.zh_CN
dc.language.isozhzh_CN
dc.publisher厦门大学《电化学》编辑部zh_CN
dc.relation.ispartofseries研究论文zh_CN
dc.relation.ispartofseriesArticleszh_CN
dc.source.urihttp://electrochem.xmu.edu.cn/CN/abstract/abstract9722.shtmlzh_CN
dc.subjectAnedic film on leadzh_CN
dc.subjectt-PbOzh_CN
dc.subjecto-PbOzh_CN
dc.subjectObO·PbSO_4zh_CN
dc.title硫酸溶液中铅阳极膜研究的几个问题(-)zh_CN
dc.title.alternativeProblems on the Study of Anodic Films on Pb in Sulfuric Acid Solution(Ⅰ)zh_CN
dc.typeArticlezh_CN
dc.description.note作者联系地址:复旦大学化学系zh_CN
dc.description.noteAuthor's Address: Department of Chemistry,Fudan University,Shanghai 200433zh_CN


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