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dc.contributor.author邓顺柳zh_CN
dc.contributor.author谢素原zh_CN
dc.date.accessioned2011-04-26T08:03:52Z
dc.date.available2011-04-26T08:03:52Z
dc.date.issued2011-01zh_CN
dc.identifier.citation化学进展,2011,23(1):53-64zh_CN
dc.identifier.issn1005-281Xzh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/2503
dc.description通讯作者地址: Deng, SL (通讯作者), Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 2. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 电子邮件地址: sldeng@xmu.edu.cnzh_CN
dc.description.abstract[中文文摘]富勒烯是一类由12 个五元环和若干六元环组成的笼状分子,自20 世纪80 年代中期被发现 以来就以其独特的结构和新奇的性质而成为科学界研究的热点,25 年来,无论在基础研究还是在实际应用 领域都有了长足的进步,人们在发展富勒烯合成新方法和寻找富勒烯新结构方面做了大量的工作。本文对 富勒烯的各种宏量合成方法进行了回顾,并概述了迄今已发表的60 余种富勒烯新结构,包括各种富勒烯空 笼、内嵌富勒烯、富勒烯笼外修饰衍生物及氮杂富勒烯等结构。[英文文摘]Fullerenes are a class of cage-like molecules made of hexagons and exactly twelve pentagons. Since the discovery of fullerene in the middle of 1980's, the chemistry of fullerenes has become a flourishing field as a result of their unique structures and remarkable properties. In the past twenty-five years, significant progress has been achieved in both fundamental and practical fields. Efforts have been made to improve synthetic efficiency and to synthesize new species of fullerene cage. Herein we review the methods for fullerene synthesis and the novel cage geometries (more than 60 fullerene structures) that have been retrieved and characterized to date. Advances in the production, separation and characterization of various fullerenes are presented, including hollow fullerenes, endohedral fullerenes, exohedral derivatives of fullerenes and azafullerenes.zh_CN
dc.language.isozhzh_CN
dc.publisher《化学进展》编辑部zh_CN
dc.subject富勒烯zh_CN
dc.subject合成zh_CN
dc.subject结构zh_CN
dc.subject内嵌富勒烯zh_CN
dc.subject笼外化学修饰zh_CN
dc.subjectIPR 规则zh_CN
dc.subject氮杂富勒烯zh_CN
dc.subjectfullereneszh_CN
dc.subjectsynthesiszh_CN
dc.subjectstructurezh_CN
dc.subjectendohedral fullereneszh_CN
dc.subjectexohedral derivatizationzh_CN
dc.subjectIPRzh_CN
dc.subjectazafullereneszh_CN
dc.title富勒烯合成化学研究进展zh_CN
dc.title.alternativeSynthetic Chemistry of Fullereneszh_CN
dc.typeArticlezh_CN


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