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dc.contributor.authorWang, Fang-Kuozh_CN
dc.contributor.authorYang, Shi-Yaozh_CN
dc.contributor.author杨士烑zh_CN
dc.contributor.authorHuang, Rong-Binzh_CN
dc.contributor.author黄荣彬zh_CN
dc.contributor.authorZheng, Lan-Sunzh_CN
dc.contributor.author郑兰荪zh_CN
dc.contributor.authorBatten, Stuart R.( Monash Univ, Sch Chem)zh_CN
dc.date.accessioned2011-04-26T08:03:04Z
dc.date.available2011-04-26T08:03:04Z
dc.date.issued2008zh_CN
dc.identifier.citationCrystEngComm, 2008, 10(9): 1211-1215zh_CN
dc.identifier.issn1466-8033zh_CN
dc.identifier.urihttp://dx.doi.org/doi:10.1039/B718995Hzh_CN
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/2033
dc.description.abstractBy tuning the ratio of solvents in a binary solvent mixture, the coordination geometries of the metal centers were controlled and three 2Dcoordination polymers, [Zn(bdc)(dma)](n)1, [Zn-3(bdc)(3)(dma)(2)](n)2 and {[Zn(bdc)(H2O)]center dot(DMA)}(n)3, were synthesized from zinc(II) nitrate and H(2)bdc in water/DMA solvents (H(2)bdc benzene-1,4-dicarboxylic acid, DMA N, N-dimethylacetamide). As the ratio of water/DMA increases, the number of DMA ancillary ligands coordinated to the zinc ion decreases, until all the DMA are substituted by water. The change in the ratio of solvents ( which also act as ancillary ligands) affords a means to adjust the local coordination environment of the zinc ion, leading to three types of SBUs, which further determine the topologies and the packing modes of the coordination polymers.zh_CN
dc.language.isoenzh_CN
dc.publisherROYAL SOC CHEMISTRYzh_CN
dc.titleControl of the topologies and packing modes of three 2D coordination polymers through variation of the solvent ratio of a binary solvent mixturezh_CN
dc.typeArticlezh_CN


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