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有序介孔碳载钯的制备、表征及对甲酸的电催化氧化性能
Electrooxidation of Formic Acid on Palladium Nanoparticles Supported on Ordered Mesoporous Carbon

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有序介孔碳载钯的制备_表征及对甲酸的电催化氧化性能.pdf (469.4Kb)
Date
2012-02
Author
陈明晖
贺春兰
张斌伟
姜艳霞
陈声培
孙世刚
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  • 化学化工-已发表论文 [14469]
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Abstract
[中文文摘]通过浸渍法和硫引入贵金属法分别制备了主要负载在介孔碳主孔道(MPC/Pd-1)和负载在介孔碳孔壁上小介孔中[MPC/(S)Pd-2]的两类负载型钯电催化剂,用XRD,SEM,TEM和电化学等方法表征了其结构和电催化性能.循环伏安结果表明,有序介孔碳载钯催化剂MPC/Pd-1和MPC/(S)Pd-2对甲酸氧化的催化活性分别是商用钯黑催化剂的4.0和2.4倍.MPC/Pd-1中的钯位于介孔碳的主孔道上,增加了催化剂/电解质/反应物三相界面的面积,使得其比MPC/(S)Pd-2的催化活性更高.[英文文摘]Ordered mesoporous carbon(MPC) supported palladium catalysts were prepared by impregnation(MPC/Pd-1) and the method of using sulfur to embed noble metal,respectively.The properties of the MPC/Pd were investigated by XRD,HRTEM,BET and electrochemical methods.Cyclic voltammetry and current-time curve show that MPC/Pd exhibits a very high catalytic activity for the oxidation of formic acid,which is 4.0(MPC/Pd-1) and 2.4 times that of commercial Pd black.Pd nanoparticles on MPC/Pd-1 are confined in the pores of...of MPC( 5—6 nm),which increases the reaction interfaces of the three-phase boundary( catalyst-electrolyte-reactive),whereas Pd nanoparticles on MPC /( S) Pd-2 are loaded inside the small mesoporous of the pore wall( 2—3 nm) ,which decreases utilization of the catalyst.
Description
联系人简介: 孙世刚,男,博士,教授,博士生导师,主要从事表面电化学研究. E-mail: sgsun@ xmu. edu. cn 姜艳霞,女,博士,教授,主要从事电催化研究. E-mail: yxjiang@ xmu. edu. cn国家自然科学基金(批准号:20833005,20873116,60936003)资助
Citation
高等学校化学学报,2012,33(2):331-335
URI
https://dspace.xmu.edu.cn/handle/2288/18850

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