5-羟甲基糠醛还原胺化制备5-氨甲基-2-呋喃甲醇类化合物的研究
Study on the Preparation of 5-Aminomethyl-2-furanmethanol Compounds by the Reductive Amination of 5-Hydroxymethylfurfural
摘要
生物质是唯一可以替代化石资源为人类提供燃料、材料和化学品的可再生资源，生物质经平台分子转化为高附加值的化学品是生物质资源利用的重要途径之一。5-羟甲基糠醛（5-Hydroxymethylfurfural，HMF）是一种重要的生物质基平台化合物，通过HMF的还原胺化可以将生物质转化为5-氨甲基-2-呋喃甲醇类化合物。本论文以转化平台分子实现生物质的高值化利用为目标，围绕HMF还原胺化制备5-[（二甲氨基）甲基]-2-呋喃甲醇（5-[(Dimethylamino)methyl]-2-furanylmethanol，DMMF）和5-氨甲基-2-呋喃甲醇（5-Aminomethyl-2-furanme... Biomass is considered to be the only renewable resources in nature to replace the fossil resources for producing fuels, chemicals and materials. The conversion of biomass into value-added chemicals via platform molecule is one of the most important pathway for the utilization of biomass. 5- Hydroxymethylfurfural (HMF) is one of the most important biomass-derived platform molecules, and the biomass...