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dc.contributor.advisor王泉明
dc.contributor.advisor林玉妹
dc.contributor.author汪剑宇
dc.date.accessioned2018-12-05T01:11:18Z
dc.date.available2018-12-05T01:11:18Z
dc.date.issued2018-07-17
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/168476
dc.description.abstract近年来,阴离子模板法应用于高核银簇的合成受到人们极大的关注。阴离子模板可以控制团簇的形状和尺寸,还深刻影响团簇的物理化学性质。引入新型的阴离子为模板是构筑结构新颖、性质优良的高核银簇合物的重要手段。本文通过不同的方法引入多样化的阴离子,包括简单的无机阴离子[ReO4]-、复杂的多酸阴离子[Mn3Mo14O56]17-,[MnMo6O24]6-以及碳负离子等,合成了一系列有趣的高核银簇合物,并发现了银簇的包裹形式对于稳定一些特殊的阴离子有重要作用。 论文主要有以下内容: 一、以NH4ReO4为前驱体合成银簇合物。将NH4ReO4和AgC≡CtBu和AgSbF6反应可以得到簇合物Ag24(C≡...
dc.description.abstractIn recent years, the anionic template used in high silver clusters nuclear synthesis is of great concern. Anionic template can control the shape and size of the clusters, but also a profound impact on the physical and chemical properties of the clusters. The introduction of new anion as a template is an important means to build a new structure, excellent properties of high nuclear Silver Clusters....
dc.language.isozh_CN
dc.relation.urihttps://catalog.xmu.edu.cn/opac/openlink.php?strText=51381&doctype=ALL&strSearchType=callno
dc.source.urihttps://etd.xmu.edu.cn/detail.asp?serial=55803
dc.subject"阴离子模板"
dc.subject"银簇"
dc.subject"多酸"
dc.subject"超配位化合物"
dc.subjectAnion template, "hypercoordination carbon atom"
dc.subject"silver cluster"
dc.subject"polyoxometalate"
dc.title阴离子导向的高核银簇的合成与表征
dc.title.alternativeThe Synthesis and Characterization of Anion-Templated High-nuclear Silver Clusters
dc.typethesis
dc.date.replied2016-05-25
dc.description.note学位:理学硕士
dc.description.note院系专业:化学化工学院_物理化学
dc.description.note学号:20520131151635


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