Palladium(II)-Catalyzed Hydration of Alkynylphosphonates to beta-Ketophosphonates
Date
2012-09Author
Li, Xiubin
Hu, Gaobo
Luo, Ping
Tang, Guo
Gao, Yuxing
Xu, Pengxiang
Zhao, Yufen
赵玉芬
Collections
- 化学化工-已发表论文 [14469]
Abstract
A highly efficient palladium(II)-catalyzed hydration of a wide range of alkynylphosphonates to the corresponding beta-ketophosphonates has been developed to give high yields at 80 degrees C in 1, 4-dioxane, with no acidic or alkaline cocatalysts required. The described catalytic system should provide an efficient alternative to highly toxic mercury-catalyzed methodologies and be useful in synthetic programs.
Citation
ADVANCED SYNTHESIS & CATALYSIS,2012,354(13):2427-2732URI
http://dx.doi.org/10.1002/adsc.201200420WOS:000308329300012
https://dspace.xmu.edu.cn/handle/2288/14734