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dc.contributor.author杨森根
dc.contributor.author唐田
dc.contributor.author林永生
dc.contributor.author程大典
dc.contributor.author詹梦熊
dc.contributor.author郑兰荪
dc.date.accessioned2017-11-14T01:48:05Z
dc.date.available2017-11-14T01:48:05Z
dc.date.issued2001-03-15
dc.identifier.citation高等学校化学学报,2001,(02):24-26
dc.identifier.issn0251-0790
dc.identifier.otherGDXH200102005
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/143228
dc.description.abstractThe fullerene complexes, η~2-C_70[RhCl(CO)(PPh_3)_2]_n(n=1, 2), have been prepared by the reaction of C_70 with RhCl(CO)(PPh_3)_2 in methylbenzene at room temperature. The new complexes were characterized by UV-Vis spectra, IR, XPS and elemental analysis. The results show that the complexes of η~2 form can be formed by RhCl(CO)(PPh_3)_2 bonding to C_70 in theσ-π way. In addition, the complexes structures have been supposed.
dc.description.sponsorship国家自然科学基金!(批准号 :2 94710 2 4);; 高等学校博士学科点专项科研基金!(批准号 :980 38410 )资助
dc.language.isozh_CN
dc.subjectC_(70)[RhCl(CO)(PPh_3)_2]_2
dc.subjectC_(70)[RhCl(CO)(PPh_3)_2]
dc.subject合成
dc.subject表征
dc.subjectC_70[RhCl(CO)(PPh_3)_2]_2
dc.subjectC_70[RhCl(CO)(PPh_3)_2]
dc.subjectSynthesis
dc.subjectCharacterization
dc.titleη~2C_(70)[RhCl(CO)(PPh_3)_2]_n配合物的合成和表征
dc.title.alternativeSynthesis and Characterization for Complexesη~2-C_(70)[RhCl(CO)(PPh_3)_2]_n
dc.typeArticle


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