Synthesis and Characterization for Complexesη~2-C_(70)[RhCl(CO)(PPh_3)_2]_n
- 化学化工－已发表论文 
The fullerene complexes, η~2-C_70[RhCl(CO)(PPh_3)_2]_n(n=1, 2), have been prepared by the reaction of C_70 with RhCl(CO)(PPh_3)_2 in methylbenzene at room temperature. The new complexes were characterized by UV-Vis spectra, IR, XPS and elemental analysis. The results show that the complexes of η~2 form can be formed by RhCl(CO)(PPh_3)_2 bonding to C_70 in theσ-π way. In addition, the complexes structures have been supposed.