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dc.contributor.author覃世辉
dc.contributor.author吴振奕
dc.contributor.author杨绳岩
dc.contributor.author詹梦熊
dc.date.accessioned2017-11-14T01:47:02Z
dc.date.available2017-11-14T01:47:02Z
dc.date.issued2007-05-15
dc.identifier.citation厦门大学学报(自然科学版),2007,(03):148-150
dc.identifier.issn0438-0479
dc.identifier.otherXDZK200703031
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/142761
dc.description.abstract富勒烯金属配合物具有特殊的物理和化学性质.本实验在氮气氛中采用配体取代法合成了富勒烯Ru金属配合物C60RuCl2(phCH2Pph2)2,并利用元素分析、红外光谱、紫外可见光谱、光电子能谱、X射线多晶粉末衍射对配合物的组成、结构等进行了表征.结果表明,C60以σ──π配位方式与Ru形成了稳定的η2型C60金属配合物C60RuCl2(phCH2Pph2)2.
dc.description.abstractFullerene-ruthenium metal complexe C60RuCl2(phCH2Pph2)2 was synthesized using the method of ligand substitution via the reaction of C60 with RuCl2(phCH2Pph2)4 under condition of a nitrogen atmosphere and refluxing.The title compound was characterized by using elemental analysis,infrared spectroscopy,UV-vis,XPS,XRD.The results showed that the phCH2Pph2 took up tow coordination sites of the central metal,and C60 took up another two sites in σ π feedback pattern.
dc.description.sponsorship福建省自然科学基金项目(E04100001,E0110002)资助
dc.language.isozh_CN
dc.subject富勒烯
dc.subject钌配合物
dc.subject配体取代
dc.subjectfullerene
dc.subjectruthenium comples
dc.subjectligand substituting
dc.titleC_(60)RuCl_2(phCH_2Pph_2)_2的合成与表征
dc.title.alternativeSynthesis and Characterization of the Fullerene Complex C_(60)RuCl_2(phCH_2Pph_2)_2
dc.typeArticle


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