Synthesis, Characterization and Photovoltaic Effect of Porphyrin-Fullerene Compounds MP-C_(60)
- 化学化工－已发表论文 
The convalently linked porphyrin-fullerene ligand was synthesized by 1,3 dipolar cycloaddition reaction. The ligand and complexes were characterized by means of FT-IR, Uv-Vis, ~1HNMR, ESI-MS and elemental analysis. The photoelectricity transform performance of the compounds was studied.The result indicated that the photovoltaic effect of (n+n) heterojunction electrode formed by MP-C_(60)/GaAs was super, especially in the I_2/I_3~- and O_2/H_2O redox couples, and photovoltaic potential was preferable.The photovoltaic performance of a MP-C_(60)/GaAs electrode at 1-2 μm thinck MP-C_(60) film of appeared peak value.