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dc.contributor.authorYAN, WB
dc.contributor.author颜文斌
dc.contributor.authorZHOU, ZH
dc.contributor.author周朝晖
dc.contributor.authorZHANG, H
dc.contributor.author章慧
dc.contributor.authorTANG, XY
dc.contributor.author唐星原
dc.contributor.authorXU, ZG
dc.contributor.author徐志固
dc.date.accessioned2012-10-11T01:08:16Z
dc.date.available2012-10-11T01:08:16Z
dc.date.issued1995
dc.identifier.citationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1995,16(1):133-135zh_CN
dc.identifier.issn0251-0790
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/13726
dc.description.abstractKinetic studies of the outer-sphere electron transfer reaction between [Co(tmen)(3)](3+) and [Fe(CN)(6)](4-) have been carried out at various temperatures and pH values. The ion-pair formation constant Q(ip) of the precursor complex [Co(tmen)(3)](3+)- [Fe(CN)(6)](4-) is 5.6 X 10(2) L . mol(-1) and the rate constant k(et) for the electron transfer within the ion-pair is 6.8 X 10(-3) s(-1) at 25 degrees C and I= 0.10 mol/L. The activation enthalpy Delta H-et(not equal) and the activation entropy Delta H(et)not equal of this reaction are 1.6 X 10(2) kJ/mol and 6.5 X 10(2) J/mol . K respectively. The mechanism of the reaction is discussed.zh_CN
dc.language.isozhzh_CN
dc.publisherHIGHER EDUCATION PRESSzh_CN
dc.subjectELECTRON TRANSFER REACTIONzh_CN
dc.subjectOUTER-SPHERE MECHANISMzh_CN
dc.subjectTRICHLOROTRITETRAMETHYL-ETHYLENEDIAMINE COBALT(II)zh_CN
dc.titleKINETIC INVESTIGATION OF THE REDUCTION FOR CROWDED [CO(TMEN)(3)](3+) BY [FE(CN)(6)](4-)zh_CN
dc.typeArticlezh_CN


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