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dc.contributor.authorWu, LL
dc.contributor.author吴玲玲
dc.contributor.authorLuo, J
dc.contributor.author罗谨
dc.contributor.authorLin, ZH
dc.contributor.author林仲华
dc.date.accessioned2012-08-08T01:30:33Z
dc.date.available2012-08-08T01:30:33Z
dc.date.issued1997
dc.identifier.citationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1997,18(10):1657-1663zh_CN
dc.identifier.issn0251-0790
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/13439
dc.description.abstractThe redox mechanism of the conducting polymer film of poly-o-phenylenediamine (P-o-PD) in acid solution has been studied by cyclic voltammetry(CV), electrochemical insitu resonance Raman spectroscopy and UV-Vis subtractive reflectance spectroscopy, The results of the CV show that the redox process of P-o-PD is controlled by the surface processes and three steady redox states are formed in the redox process, The in-situ resonance Raman spectra not only verify the existence of the three steady states of P-o-PD, but also indicate that the structure of P-o-PD is dominated by a ladder polymer with phenazine rings, The three kinds of P-o-PD display different stabilities and UV-Vis aborption spectra, Furthermore, the in-situ time-resolved UV-Vis reflectance spectroscopy is used to study the dynamic redox process of P-o-PD, and a possible reaction mechanism is proposed at last.zh_CN
dc.language.isozhzh_CN
dc.publisherHIGHER EDUCATION PRESSzh_CN
dc.subjectspectroelectrochemistryzh_CN
dc.subjectpoly-o-phenylenediaminezh_CN
dc.subjectredox mechanismzh_CN
dc.titleSpectroelectrochemical studies of the conducting polymer of o-phenylenediaminezh_CN
dc.typeArticlezh_CN


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