Cathodic disbonding of a thick polyurethane coating from steel in sodium chloride solution
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The cathodic disbonding of a thick, pigmented polyurethane coating from steel in 3.5 wt.% NaCl solution was studied by using an electrochemical AC impedance technique. Double-cylinder electrolyte cells were designed to separate the measurements of cathodic disbonding process from the influence of the impedance of an artificial defect. It was found that for a thick, pigmented polyurethane coating, the more important transport pathway of the reactive species is along the coating/steel interface rather than through the coating. There existed a delay time for the cathodic disbonding process, and cathodic polarization was not a predominant factor in determining the cathodic disbonding behavior in the early stages. The thick polyurethane coating, which was applied on a well sand-blasted steel surface, had excellent resistance to cathodic disbonding. (C) 1997 Elsevier Science S.A.
出处PROGRESS IN ORGANIC COATINGS，1997,31（4）：289-295