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dc.contributor.authorChen, X
dc.contributor.author陈曦
dc.contributor.authorJia, L
dc.contributor.author贾丽
dc.contributor.authorSato, M
dc.date.accessioned2012-08-01T01:22:18Z
dc.date.available2012-08-01T01:22:18Z
dc.date.issued1998
dc.identifier.citationACTA CHIMICA SINICA,1998,56(3):238-243zh_CN
dc.identifier.issn0567-7351
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/13382
dc.description.abstractThe luminescent electrooxidation of methanol in tris(2,2'-bipyndine) ruthenium (II)[Ru(bpy)(3)(2+)] alkaline solution on a glassy carbon electrode has been studied. At the potential of +1.28V (vs. Ag/AgCl), methanol was oxidized to methoxyl radical, and the excited formaldehyde was generated by a disprotionation reaction of the methoxyl radical to yield light emission with the wavelength of 545 nm. Brighter light emission could be found if small amount of Ru(bpy)(3)(2+) was added. The luminescent wavelength was 608 nm because Ru(bpy)(3)(2+) was oxidized to Ru(bpy)(3)(2+) and reacted with methoxyl radical to produce the excited state of Ru(bpy)(3)(2+*).zh_CN
dc.language.isozhzh_CN
dc.publisherACTA CHIMICA SINICAzh_CN
dc.subjectelectrochemiluminescencezh_CN
dc.subjectmethanolzh_CN
dc.subjecttris(2,2 '-bipyridine) ruthenium(II)zh_CN
dc.titleStudy on the electrochemiluminescence based on tris(2,2 '-bipyridine)ruthenium and methanolzh_CN
dc.typeArticlezh_CN


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