Formation and photoelectrochemical properties of charge transfer complexes between fullerene and metallophthalocyanine
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The formation of charge transfer complexes (CTC) between C-60 with metallophthalocyanine (MPc. M=Zn, Co) has been investigated in three mixed organic solvents. The MPc-C-60 CTC were characterized by using UV-Vis and fluorescence spectra. The formation equilibrium constants (K) of CTC and their stoichiometry were determined. The foundation of CTC leads to a remarkable enhancement of the photoelectrochemical property. The CTC will provide a potential opportunity to develop a new applicable photoelectric material.