Show simple item record

dc.contributor.authorZeng, Y
dc.contributor.authorZhou, SM
dc.contributor.author周绍民
dc.date.accessioned2012-07-02T01:48:40Z
dc.date.available2012-07-02T01:48:40Z
dc.date.issued1999-08-05
dc.identifier.citationCHINESE CHEMICAL LETTERS,1999,10(10):863-866zh_CN
dc.identifier.issn1001-8417
dc.identifier.urihttp://dx.doi.org/10.1016/S1388-2481(99)00043-0
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/13073
dc.description.abstractThe electrocatalytic oxidation of hypophosphite on a nickel electrode has been studied by means of in situ UV-Vis subtractive reflectance spectroscopy. An absorbency band around 245 nm, which was ascribed to the formation of an intermediate, (PHO2-)-P-., was observed in the electrocatalytic oxidation process. Accordingly, the electrocatalytic oxidation of hypophosphite might undergo a H abstraction of hypophosphite from the P-H bond to form the phosphorus-centred radical (PHO2-)-P-.. which is subsequently electrooxidized to the final product, phosphite.zh_CN
dc.language.isoenzh_CN
dc.publisherCHINESE CHEMICAL SOCIETYzh_CN
dc.subjectin situ UV-Vis subtractive reflectance spectroscopyzh_CN
dc.subjectelectrooxidationzh_CN
dc.subjecthypophosphitezh_CN
dc.subjectmechanismzh_CN
dc.titleElectrocatalytic oxidation of hypophosphite on nickel electrode - In situ UV-Vis spectroscopic studyzh_CN
dc.typeArticlezh_CN


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record