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dc.contributor.authorLiang, FP
dc.contributor.author梁福沛
dc.contributor.authorHu, RX
dc.contributor.author胡瑞祥
dc.contributor.authorPan, ET
dc.contributor.author潘恩霆
dc.contributor.authorTang, XL
dc.contributor.author唐献兰
dc.contributor.authorLiang, H
dc.contributor.author梁宏
dc.contributor.authorZhou, ZH
dc.contributor.author周朝晖
dc.date.accessioned2012-07-01T00:59:36Z
dc.date.available2012-07-01T00:59:36Z
dc.date.issued2000
dc.identifier.citationCHINESE JOURNAL OF INORGANIC CHEMISTRY,2000,16(1):139-143zh_CN
dc.identifier.issn1001-4861
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/13056
dc.description.abstractThe Lanthanum picrate complex with 1, 10-phenanthroline was synthesized, whose chemical formula can be written in [La(pic)(3)(phen)(2)] . CH3CN. The crystal X-ray diffraction analysis shows that crystal belongs to monoclinic with space group P2(1)/a and unit cell parameters: a = 17.072 (4), b = 16.083(4), c = 17.789(4), beta = 106.34(2)degrees V = 4687(4) (3), Z = 4, Dc = 1.735g.cm(3), mu = 10.106cm(-1), F(000) = 2448, R = 0.0589, Rw = 0.0589. The coordination number of La3+ is nine. Acetonitrile, a solvent molecule is not coordinated. Between three Pic ligands, that possesses 2 bidentate forms six-member ring with La. The other is unidentate ligand. As usually, phen is bidentate ligand.zh_CN
dc.language.isozhzh_CN
dc.publisherCHINESE CHEMICAL SOCIETYzh_CN
dc.subjectlanthanumzh_CN
dc.subjectpicratezh_CN
dc.subject1,10-phenanthrolinezh_CN
dc.subjectcomplexzh_CN
dc.subjectcrystal structurezh_CN
dc.titleSynthesis and crystal structure of [La(pic)(3)(phen)(2)]center dot CH3CNzh_CN
dc.typeArticlezh_CN


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