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dc.contributor.authorGao, JX
dc.contributor.author高景星
dc.contributor.authorYi, XD
dc.contributor.author伊晓东
dc.contributor.authorXu, PP
dc.contributor.authorTang, CL
dc.contributor.authorZhang, H
dc.contributor.authorWan, HL
dc.contributor.author万惠霖
dc.contributor.authorIkariya, T
dc.date.accessioned2012-06-17T01:41:52Z
dc.date.available2012-06-17T01:41:52Z
dc.date.issued2000-07-24
dc.identifier.citationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2000,159(1):3-9zh_CN
dc.identifier.issn1381-1169
dc.identifier.urihttp://dx.doi.org/10.1016/S1381-1169(00)00163-1
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/12807
dc.description.abstractThe interaction of [Rh(COD)Cl](2) with two equivalents of (S)-N,N'-bis[o-(diphenylphosphino)benzylidene]propane-1,2-diamine [(S)-1] or (S)-N,N'-bis[o-(diphenylphosphino)benzyl]propane-1,2-diamine [(S)-2] in benzene/methanol mixture and then precipitation by the addition of a solution of NH,PF, in water afforded cationic rhodium(I) complexes [Rh(S)-MeP2N2][PF6] and [Rh(S)-MeP2(NH)(2)][PF6] in good yield, respectively. Complexes [Rh(R,R)-C6P2N2][PF6] and [Rh(R,R)-C6P2(NH)(2)][PF6] were also prepared by an analogous manner. All these rhodium complexes have been characterized by analytical and spectroscopic methods and their asymmetric catalytic properties for enantioselective transfer hydrogenation of acetophenone have been tested. [Rh(R,R)-C6P2(NH)(2)][PF6] was used as an excellent catalyst precursor for enantioselective transfer reduction of acetophenone in 2-propanol, leading to 2-phenylathanol in 97% yield and in 91% ee after 7 h at 83 degrees C. (C) 2000 Elsevier Science B.V. All rights reserved.zh_CN
dc.language.isoenzh_CN
dc.publisherELSEVIER SCIENCE BVzh_CN
dc.subjectcationic rhodium complexeszh_CN
dc.subjectenantioselective reductionzh_CN
dc.subjectsimple ketoneszh_CN
dc.titleCationic rhodium complexes with chiral tetradentate ligands as catalysts for enantioselective reduction of simple ketoneszh_CN
dc.typeArticlezh_CN


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