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dc.contributor.authorChen, SP
dc.contributor.author陈声培
dc.contributor.authorHuang, GX
dc.contributor.author黄国贤
dc.contributor.authorSun, SG
dc.contributor.author孙世刚
dc.date.accessioned2012-06-15T01:17:50Z
dc.date.available2012-06-15T01:17:50Z
dc.date.issued2000
dc.identifier.citationSPECTROSCOPY AND SPECTRAL ANALYSIS,2000,20(5):630-631zh_CN
dc.identifier.issn1000-0593
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/12778
dc.description.abstractIn this paper, the electrochemical cyclic voltammetry,UV/Vis and in situ FTIR spectroscopy were used to study the electrochemical reduction of [Os-VI (N)(NH3)(4)](CF3SO3)(3) on GC and Pt electrode in acetonitrile. The results demonstrated that the N-N coupling can occur between [Os-VI(N)(NH3)(4)](3+) and the osmium(V) species generated at the electrode. It has revealed for the first time,by in situ FTIR spectroscopy, that the IR absorption of the nu>(*) over bar * (N=N) mode of the mu -dinitrogen osmium [III, II] and [II, II] complex yields positive-going band at around 2 019 cm(-1) and negative-going band near 1 970 cm(-1),respectively. The results provided new insights in understanding the mechanism of the coupling reaction [Os-V=N] [Os-VI=N][Os-VI=N]<=>[Os-II-N=N-Os-II].zh_CN
dc.language.isozhzh_CN
dc.publisherBEIJING UNIV PRESSzh_CN
dc.subjectin situ FTIRSzh_CN
dc.subjectUV/VISzh_CN
dc.subject[Os-VI(N)(NH3)(4)](CF3SO3)(3)zh_CN
dc.titleIn situ FTIRS studies of reduction of [Os-VI(N)(NH3)(4)](CF3SO3)(3) in acetonitrilezh_CN
dc.typeArticlezh_CN


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