In-situ FTIR spectroscopic studies of electro oxidation of ethanol in alkaline media at a nm-Pt/GC electrode
Date
2000Author
Chen, GL
陈国良
Sun, SG
孙世刚
Chen, SP
陈声培
Zheng, MS
郑明森
Xia, SQ
夏盛清
Wu, QH
吴起辉
Zhou, ZY
周志有
Jiang, YX
姜艳霞
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- 化学化工-已发表论文 [14469]
Abstract
The electro-oxidation of ethanol on a nm-Pt/GC electrode in alkaline solutions was investigated by using cyclic Voltammetry and in-situ FTIR spectroscopy. The results demonstrated that the main product of ethanol oxidation was CH3 COO-, only small quantity of CH3 CHO was determined simultaneously. In contrast with the dual path reaction mechanism for the oxidation of ethanol in acid media, the oxidation of ethanol in alkaline media was revealed via the intermediate process of dissociative adsorption.