Show simple item record

dc.contributor.authorShao, CP
dc.contributor.authorChen, MS
dc.contributor.author陈明树
dc.date.accessioned2012-06-10T02:04:25Z
dc.date.available2012-06-10T02:04:25Z
dc.date.issued2001-02-09
dc.identifier.citationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2001,166(2):331-335zh_CN
dc.identifier.issn1381-1169
dc.identifier.urihttp://dx.doi.org/10.1016/S1381-1169(00)00479-9
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/12697
dc.description.abstractThe in situ FT-IR spectra were used to study the CO2 hydrogenation reactions over the SiO2-supported heterobinuclear metal complex catalysts, RhM (M = Cr, Mo, W). The bands, which correspond to the formate species adsorbed on the catalysts, were observed. During the hydrogenation reactions, the adsorbed linear and bridged bridging CO were not observed. The experimental results suggest that for the CO2 and CO hydrogenation reactions over the same catalysts, their catalytic active intermediate species and the reaction mechanisms should be different. (C) 2001 Elsevier Science B.V. All rights reserved.zh_CN
dc.language.isoenzh_CN
dc.publisherELSEVIER SCIENCE BVzh_CN
dc.subjectCO2 hydrogenationzh_CN
dc.subjectin situ FT-IRzh_CN
dc.subjectbimetal complex catalystzh_CN
dc.titleIn situ FT-IR studies on the CO2 hydrogenation over the SiO2-supported RhM (M = Cr, Mo, W) complex catalystszh_CN
dc.typeArticlezh_CN


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record