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Bond valence parameters linearly dependent on the molybdenum oxidation states

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Bond valence parameters linearly dependent on the molybdenum oxidation states.pdf (227.6Kb)
Date
2002
Author
Chen, MD
Zhou, ZH
周朝晖
Hu, SZ
胡盛志
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  • 化学化工-已发表论文 [14469]
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Abstract
Based on the available crystal data, a linear correlation between R-0, the bond valence parameter for a Mo-containing chemical bond, and the Mo oxidation state n was developed for the first time. Using the "universal" value of the parameter B = 0.037 nm, the linear equations of R-0-n for Mo-X (X: 0, S, N, Cl and F) bonds were established. The oxidation-state independent Mo-O bond valence parameters, R-0 = 0.18788 nm and B = 0.03046 nm, published recently have been shown to be a special case of the linearly correlated functions. Some bond valence sum calculations in compounds containing only Mo-O bonds using these parameters are presented.
Citation
CHINESE SCIENCE BULLETIN,2002,47(12):978-981
URI
http://dx.doi.org/doi:10.1007/BF02907564
https://dspace.xmu.edu.cn/handle/2288/12424

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