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Fe-MCM-41 catalyzed epoxidation of alkenes with hydrogen peroxide

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Fe-MCM-41 catalyzed epoxidation of alkenes with hydrogen peroxide.htm (413bytes)
Date
2007-06-08
Author
Zhang, QH
张庆红
Wang, Y
王野
Itsuki, S
Shishido, T
Takehira, K
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  • 化学化工-已发表论文 [14469]
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Abstract
Fe-MCM-41 has been characterized in detail and studied for epoxidation of alkenes with H2O2. UV-vis, ESR, Fe K-edge XAFS and UV-Raman spectroscopic studies suggest that iron in Fe-MCM-41 is highly dispersed and mainly incorporated into the framework of MCM-41. Fe-MCM-41 is effective for epoxidation of alkenes including styrene, cyclohexene and many other cyclic alkenes with H2O2. The tetrahedrally coordinated iron sites in the framework of MCM-41 are probably responsible for the epoxidation reactions.
Citation
NANOTECHNOLOGY IN MESOSTRUCTURED MATERIALS,2003,146:625-628
URI
http://dx.doi.org/10.1016/S0167-2991(03)80461-5
https://dspace.xmu.edu.cn/handle/2288/12229

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