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Carbon fibers prepared by pyrolysis of methane over Ni/MCM-41 catalyst

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Carbon fibers prepared by pyrolysis of methane over NiMCM-41 catalyst.htm (413bytes)
发布日期
2003-12-27
作者
Jia, J
Wang, Y
王野
Tanabe, E
Shishido, T
Takehira, K
所在专题
  • 化学化工-已发表论文 [14469]
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摘要
The pyrolysis of CH4 to H-2 and carbon fibers over MCM-41 supported Ni catalyst has been investigated at different temperatures, The initial conversion of CH4 at 873 K is higher than it is at 773 K, but the deactivation at 873 K occurs rapidly. The investigations with SEM and TEM techniques indicate that the pyrolysis of CH4 generates mainly solid carbon fibers at 773 K but mostly hollow ones at 873 K on Ni/MCM-41. Ni metal particles have hardly been found on the tip of or inside the carbon fibers. Raman spectroscopic studies suggest that the carbon fibers formed at 873 K are more graphitic than those obtained at 773 K. The temperature-programmed reactions with O-2 (TPO) and H-2 (TPH) reveal that the solid carbon fibers formed at 773 K show higher reactivity towards O-2 and H-2 than the hollow ones formed at 873 K. (C) 2002 Elsevier Science Inc. All rights reserved.
出处
MICROPOROUS AND MESOPOROUS MATERIALS,2003,57(3):283-289
本条目访问地址(URI)
http://dx.doi.org/10.1016/S1387-1811(02)00598-X
https://dspace.xmu.edu.cn/handle/2288/12214

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