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dc.contributor.authorChen, W
dc.contributor.author陈卫
dc.contributor.authorSun, SG
dc.contributor.author孙世刚
dc.contributor.authorSi, D
dc.contributor.author司迪
dc.contributor.authorChen, SP
dc.contributor.author陈声培
dc.date.accessioned2012-04-24T01:59:58Z
dc.date.available2012-04-24T01:59:58Z
dc.date.issued2003
dc.identifier.citationACTA PHYSICO-CHIMICA SINICA,2003,19(5):441-444zh_CN
dc.identifier.issn1000-6818
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/12163
dc.description.abstractAgglomerates of Pt nanoparticles were synthesized by using H-2 as reduction reagent and nafion as stabilizer. The electrode of agglomerates of Pt nanoparticles was prepared by dispersing the agglomerates onto glassy carbon surface and is denoted as Pt-a(ag)/GC. The average size of the agglomerates in colloid and on the surface of electrode were characterized to be around 400 nm using TEM and SEM, respectively. Cyclic voltammetry and in situ FTIR spectroscopy were employed to study electrocatalytic properties of the Pt-a(ag)/GC electrode towards methanol oxidation. It has been revealed that the agglomerates of Pt nanoparticles exhibit significant electrocatalytic activity for the oxidation of CH3OH. In comparison with CH3OH oxidation on an electrode of Pt thin film supported on Au, the oxidation potential has been shifted negatively about 300 mV on the Pt-a(ag)/GC. The results demonstrated also that the oxidation of CH3OH is a complex process, which may be influenced by the diffusion of CH3OH and controlled by the oxidation-reduction of the agglomerates of Pt nanoparticles on electrode surface. Linearly adsorbed CO species (COL) is the only intermediate that has been determined by in situ FTIR spectroscopy. The IR features Of COL illustrated that the agglomerates of Pt nanoparticles exhibit abnormal infrared effects as other kind low-dimensional nanomaterial does.zh_CN
dc.language.isozhzh_CN
dc.publisherPEKING UNIV PRESSzh_CN
dc.subjectagglomerates of Pt nanoparticleszh_CN
dc.subjectmethanolzh_CN
dc.subjectelectrocatalytic oxidationzh_CN
dc.subjectin situ FTIRSzh_CN
dc.titleElectrocatalytic properties of agglomerates of Pt nanoparticles in methanol oxidationzh_CN
dc.typeArticlezh_CN


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