Syntheses and crystal structures of two novel zinc(II) coordination polymers
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Two novel zinc(ii) coordination polymers, [Zn-3(mu(3)-OH)(2)(nip)(2)] (1) and [Zn-2(nip)(2)(4,4'-bpy)(3).(OH2)] (2) (H(2)nip = 5-nitroisophthalic acid, 4,4'-bpy = 4,4'-bipyridyl), were obtained by the hydrothermal reactions of zinc nitrate, 5-nitroisophthalate (nip) (for 1) and zinc nitrate, 5-nitroisophthalate and 4,4'-bipyridyl (for 2). Complex 1 displays a two-dimensional structure that is built from [Zn-3(mu(3)-OH)(2)](n) chains, while complex 2 is a three-dimensional structure formed by the interpenetration of two-dimensional hydrogen-bonded bilayers. The photoluminescent properties of complex 1 have also been investigated. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
出处EUROPEAN JOURNAL OF INORGANIC CHEMISTRY，2003,14：2678-2682