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dc.contributor.authorWang, SZ
dc.contributor.author王世忠
dc.contributor.authorIshihara Tatsumi
dc.date.accessioned2012-04-13T01:16:50Z
dc.date.available2012-04-13T01:16:50Z
dc.date.issued2003
dc.identifier.citationACTA PHYSICO-CHIMICA SINICA,2003,19(9):844-848zh_CN
dc.identifier.issn1000-6818
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/12063
dc.description.abstractVarious Ni-15% Sm3+ (x) doped CeO2(Ni-SDC) composite anodes prepared by impregnation method were studied to unveil the role of SDC in improving the performance of Ni anode. The electrochemical properties and the power generation characteristics of the cells based on these anodes show that the performance of the cells were improved significantly by the addition of MC into Ni due to the reduced ohmic resistance and anodic overpotential. The decrease of anodic overpotential after the introduction of SDC could be due to the extension of three-phase-boundary(TPB) and the increase of active sites for H-2 oxidation. However, the introduction of SDC also leaded to an increase of activation energy, which resulted in a higher anodic overpotential for Ni-SDC anodes at low temperatures compared with pure Ni. The impedance spectra of Ni-SDC anode consisted of two arcs at high temperatures. The high frequency arc increased with the amount of SDC, while the low frequency arc showed no dependency on the amount of SDC. The high frequency arc could be related to the charge transfer reaction at TPB, and the low frequency arc could correspond to the disassociative adsorption of H-2 and the following diffusion processes. 75% (w) Ni-25% (w) SDC/LSGM/SSC exhibited the highest power density among the cells studied, and the highest power density at 1073, 973, 873 K reached 1. 1, 0. 43, 0. 14 W . cm(-2), respectively. The cells also showed good stability.zh_CN
dc.language.isozhzh_CN
dc.publisherPEKING UNIV PRESSzh_CN
dc.subjectsolid oxide fuel cellzh_CN
dc.subjectanodezh_CN
dc.subjectnicklezh_CN
dc.subjectsamaria doped ceria(SDC)zh_CN
dc.subjectAC impedancezh_CN
dc.titleImprovement of the performance of fuel cells anodes with Sm3+ doped CeO2zh_CN
dc.typeArticlezh_CN


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