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dc.contributor.authorLi, ZJ
dc.contributor.author李兆基
dc.contributor.authorQin, YY
dc.contributor.author覃业燕
dc.contributor.authorTang, YH
dc.contributor.author唐艳红
dc.contributor.authorKang, Y
dc.contributor.author康遥
dc.contributor.authorXia, JB
dc.contributor.author夏继波
dc.contributor.authorChen, Z
dc.contributor.author陈忠
dc.contributor.authorWu, L
dc.contributor.author吴棱
dc.contributor.authorYao, YG
dc.contributor.author姚元根
dc.date.accessioned2012-04-09T01:51:55Z
dc.date.available2012-04-09T01:51:55Z
dc.date.issued2003
dc.identifier.citationCHINESE JOURNAL OF CHEMISTRY,2003,21(9):1174-1177zh_CN
dc.identifier.issn1001-604X
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/12020
dc.description.abstractA series of carboxylate-substituted trinuclear molybdenum cluster compounds formulated as Mo3S4(DTP)(3)(RCO2) (L), where R = H, CH3, C2H5, CH2Cl, CCl3, (RC6H4)-C-1 (R-1 is the group on the benzene ring of aromatic carboxylate), L = pyridine, CH3CN, DMF, have been synthesized by the ligand substitution reaction. The dissociation of the loosely-coordinated ligand L from the cluster core was studied by P-31 NMR. The dissociation process of L is related to the solvent, temperature, and acidity of carboxylate groups, so as to affect the solution structure and reactive properties of the cluster. The long-distance interaction between ligands RCO2 and L is transported by Mo3S4 core.zh_CN
dc.language.isozhzh_CN
dc.publisherSCIENCE CHINA PRESSzh_CN
dc.subjectP-31 NMRzh_CN
dc.subjectmolybdenum clusterzh_CN
dc.subjectligand dissociationzh_CN
dc.titleP-31 NMR studies on the ligand dissociation of trinuclear molybdenum cluster compoundszh_CN
dc.typeArticlezh_CN


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