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dc.contributor.authorSun, Di
dc.contributor.authorLi, Yun-Hua
dc.contributor.authorWu, Shu-Ting
dc.contributor.authorHao, Hong-Jun
dc.contributor.authorLiu, Fu-Jing
dc.contributor.authorHuang, Rong-Bin
dc.contributor.author黄荣彬
dc.contributor.authorZheng, Lan-Sun
dc.contributor.author郑兰荪
dc.date.accessioned2012-04-07T09:28:25Z
dc.date.available2012-04-07T09:28:25Z
dc.date.issued2011-10-13
dc.identifier.citationCRYSTENGCOMM,2011,13(24):7311-7315zh_CN
dc.identifier.issn1466-8033
dc.identifier.urihttp://dx.doi.org/doi:10.1039/c1ce05672g
dc.identifier.uriWOS:000297362900023
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/12000
dc.description.abstractA novel 3D metal-organic framework (MOF), namely [Ag(12)(MA)(8)(mal)(6)center dot 18H(2)O](n) (1), (MA = melamine, H(2)mal = malonic acid) has been successfully synthesized through one-pot ultrasonic reaction of AgNO(3), MA and H(2)mal and characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. In 1, eight tridentate MA ligands coordinate to 12 Ag(I) ions to form a nanosized Ag(12) cuboctahedron with an interior diameter of 1.2 nm, which combines with the quadridentate mal anion to give 1. This is a complicated 3D MOF, which is an unprecedented (4,24)-connected net with rare twf topology when using the Ag(12) cage and mal as 24- and 4-connected nodes, respectively. Of particular importance, the unusual network topology and integrity of the framework of 1 after dehydration have also been validated and discussed in detail.zh_CN
dc.description.sponsorshipNational Natural Science Foundation of China[20721001]; MSTC[2007CB815301]zh_CN
dc.language.isoenzh_CN
dc.publisherROYAL SOC CHEMISTRYzh_CN
dc.titleAn unprecedented (4,24)-connected metal-organic framework sustained by nanosized Ag(12) cuboctahedral nodezh_CN
dc.typeArticlezh_CN


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